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Mercury lamps emit blue light with λ\lambda = 436 nm.What is the energy of these photons in joules?


A) 4.56 * 10-19 J
B) 4.56 * 10-28J
C) 1.97 * 1044 J
D) 2.19 * 1018 J
E) 2.19 * 10-18 J

F) C) and D)
G) B) and E)

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Astronomers have detected hydrogen atoms in interstellar space in the n = 732 energy level.Suppose an atom in this excited state emits a photon and undergoes a transition from n = 732 to n = 632.How much energy does the atom lose as a result of this transition? What is the frequency of this radiation? In which spectral region does this radiation lie?

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1.39 *10-24 J of en...

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What is the wavelength ( λ\lambda , in meters) of a radio station operating at a frequency of 99.6 MHz?


A) 3.01*106 m
B) 3.01 m
C) 3.32 *10-7 m
D) 0.332 m
E) 3.32 m

F) B) and E)
G) A) and C)

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What is the velocity of an O2 molecule if its de Broglie wavelength is 26 pm? (1 amu = 1.66054 *10-27 kg.)


A) 46 m/s
B) 960 m/s
C) 790 m/s
D) 390 m/s
E) 480 m/s

F) A) and E)
G) None of the above

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Orbitals within a given subshell have the same _______.


A) principal and angular momentum quantum numbers.
B) principal quantum numbers.
C) angular momentum quantum numbers.
D) angular momentum and magnetic quantum numbers.
E) angular momentum and spin quantum numbers.

F) All of the above
G) A) and D)

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Fraunhofer lines are due to _______.


A) the emission of radiation by atoms.
B) the absorption of radiation by atoms.
C) the photoelectric effect.
D) chemical reactions in the sun.
E) nuclear reactions in the sun.

F) A) and C)
G) A) and E)

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Which of the following statements about electron spin and the spin quantum number, ms, is NOT true?


A) The idea of electron spin was introduced to explain pairs of lines in atomic emission spectra.
B) The electron creates a magnetic field because it is a charged particle moving through space.
C) The spin of an electron is quantized.
D) Electrons in the same orbital can have the same spin.
E) The spin quantum number can only have one of two values, +1/2 and -1/2 .

F) B) and D)
G) A) and E)

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Copper commonly forms a cation with a charge of 1+; however, the element to the right of it in the periodic table Zn) typically only forms a cation with a 2+charge.Use your knowledge of electron configurations to explain this observation.

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Copper has the electronic conf...

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Which of the following shows the correct expression for the ionization energy indicated?


A) IE3:Al(g) Al3+(g) +3e \mathrm{IE}_{3}: \mathrm{Al}(g) \rightarrow \mathrm{Al}^{3+}(g) +3 \mathrm{e}^{-}
B) IE1:Cl(g) Cl+(g) +e \mathrm{IE}_{1}: \mathrm{Cl}(g) \rightarrow \mathrm{Cl}^{+}(g) +\mathrm{e}^{-}
C) IE2:Mg(g) Mg2+(g) +2e \mathrm{IE}_{2}: \mathrm{Mg}(g) \rightarrow \mathrm{Mg}^{2+}(g) +2 \mathrm{e}^{-}
D) IE1:Na(s) Na+(g) +e \mathrm{IE}_{1}: \mathrm{Na}(s) \rightarrow \mathrm{Na}^{+}(g) +\mathrm{e}^{-}
E) IE3:O2(g) O2+(g) +e \mathrm{IE}_{3}: \mathrm{O}_{2}(g) \rightarrow \mathrm{O}_{2}^{+}(g) +\mathrm{e}^{-}

F) D) and E)
G) A) and C)

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The Fraunhofer lines are evidence that _______.


A) atoms contain nuclei.
B) atoms contain charged particles.
C) mass is equivalent to energy.
D) atoms absorb light.
E) atoms emit light.

F) B) and D)
G) A) and B)

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Which one of the following sources produces the highest energy photons?


A) a doctor's x-ray source
B) a heat lamp in a restaurant
C) a microwave oven
D) gamma rays from a star
E) radio waves from a local station

F) All of the above
G) A) and B)

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How many unpaired electrons does nickel have?


A) 0
B) 2
C) 3
D) 4
E) 8

F) B) and C)
G) C) and D)

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Which statement below about an electron shell in a hydrogen-like atom is FALSE?


A) Higher shells are at a higher energy.
B) All electrons in the same shell occupy regions in space that have the same shape.
C) The principal quantum number, n, is used to specify a shell.
D) The size of the shell increases as n increases.
E) A shell can contain no more than N2 orbitals.

F) B) and E)
G) A) and C)

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Which of the following lasers emits photons with the lowest energy?


A) a Nd:YAG laser with λ\lambda = 1064 nm
B) an Ar+ laser with λ\lambda = 514.5 nm
C) a Kr+ laser with λ\lambda = 647 nm
D) an ArF laser with λ\lambda = 193 nm
E) a HeNe laser with λ\lambda = 633 nm

F) A) and E)
G) A) and C)

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What are the principal and angular momentum quantum numbers for a 4 f f orbital?


A) n = 4, l l = 2
B) n = 3, l l = 4
C) n = 4, l l = 3
D) n = 4, l l = 4
E) n = 4, l l = 1

F) A) and B)
G) A) and C)

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Which of the following elements would you expect to have the lowest first ionization energy?


A) N
B) As
C) P
D) Bi
E) Sb

F) B) and E)
G) C) and D)

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When the principal quantum number = 3, what values are possible for the other quantum numbers l l and ml ?

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blured image can equal 0, 1, and 2.
For blured image =...

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Which of the following is the correct electron configuration for silicon?


A) 1s22s21p63s22p2 1 s^{2} 2 s^{2} 1 p^{6} 3 s^{2} 2 p^{2}
B) 1s22s22p63s4 1 s^{2} 2 s^{2} 2 p^{6} 3 s^{4}
C) 1s22s22p63s23p2 1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{2}
D) 1s22s22p63s13p3 1 s^{2} 2 s^{2} 2 p^{6} 3 s^{1} 3 p^{3}
E) 1s22s22p62d4 1 s^{2} 2 s^{2} 2 p^{6} 2 d^{4}

F) A) and E)
G) B) and E)

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Which row 2 element probably has the following successive ionization energies: Which row 2 element probably has the following successive ionization energies:    A) Be B) B C) N D) O E) Ne


A) Be
B) B
C) N
D) O
E) Ne

F) None of the above
G) D) and E)

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Which of the following has the largest atomic radius?


A) Cs
B) Rb
C) Kr
D) Xe
E) I

F) C) and D)
G) A) and E)

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